The Wayback Machine - https://web.archive.org/web/20231107193325/https://www.science.org/doi/10.1126/science.aaf6524

Lightweight shapeshifting alloys

Shape memory alloys (SMAs) spring back into shape after they are deformed, a useful property for a variety of applications. Transition metal alloys, which are robust but dense, dominate the SMA landscape. Ogawa et al. report a new type of lightweight SMA made from magnesium and scandium, which has comparable properties to known SMAs but at significantly lower density. Although this magnesium-scandium alloy is limited to low-temperature applications, development of a new lightweight class of SMAs could be on the horizon.
Science, this issue p. 368

Abstract

Shape-memory alloys (SMAs), which display shape recovery upon heating, as well as superelasticity, offer many technological advantages in various applications. Those distinctive behaviors have been observed in many polycrystalline alloy systems such as nickel titantium (TiNi)–, copper-, iron-, nickel-, cobalt-, and Ti-based alloys but not in lightweight alloys such as magnesium (Mg) and aluminum alloys. Here we present a Mg SMA showing superelasticity of 4.4% at –150°C and shape recovery upon heating. The shape-memory properties are caused by reversible martensitic transformation. This Mg alloy includes lightweight scandium, and its density is about 2 grams per cubic centimeter, which is one-third less than that of practical TiNi SMAs. This finding raises the potential for development and application of lightweight SMAs across a number of industries.

Get full access to this article

View all available purchase options and get full access to this article.

Supplementary Material

Summary

Materials and Methods
Supplementary Text
Figs. S1 to S9
Tables S1 and S2
References (34, 35)

Resources

File (ogawa.sm.pdf)

References and Notes

1
Van Humbeeck J., Non-medical applications of shape memory alloys. Mater. Sci. Eng. A 273-275, 134–148 (1999).
2
Duerig T., Pelton A., Stöckel D., An overview of nitinol medical applications. Mater. Sci. Eng. A 273-275, 149–160 (1999).
3
Piedboeuf M. C., Gauvin R., Thomas M., Damping behavior of shape memory alloys: Strain amplitude, frequency and temperature effects. J. Sound Vibrat. 214, 885–901 (1998).
4
Santo L., Quadrini F., Accettura A., Villadei W., Shape memory composites for self-deployable structures in aerospace applications. Proc. Eng. 88, 42–47 (2014).
5
Hartl D. J., Lagoudas D. C., Aerospace applications of shape memory alloys. Proc. IMechE. 221, 535–552 (2007).
6
Ölander A., An electrochemical investigation of solid cadmium–gold alloys. J. Am. Chem. Soc. 54, 3819–3833 (1932).
7
Polmear I. J., Magnesium alloys and application. Mater. Sci. Technol. 10, 1–16 (1994).
8
Mordike B. L., Ebert T., Magnesium: Properties – applications – potential. Mater. Sci. Eng. A 302, 37–45 (2001).
9
Yang Z., Li J. P., Zhang J. X., Lorimer G. W., Robson J., Review on research and development of magnesium alloys. Acta. Metall. Sin. 21, 313–328 (2008).
10
Kulekci M. K., Magnesium and its alloys applications in automotive industry. Int. J. Adv. Manuf. Technol. 39, 851–865 (2008).
11
T. G. Byrer, E. L. White, P. D. Frost, “The development of magnesium lithium alloys for structural applications” (NASA contractor report, Battelle Memorial Institute, 1963).
12
M. M. Avedesian, H. Baker, Eds., Magnesium and Magnesium Alloys (ASM International, 1999).
13
Xu W., Birbilis N., Sha G., Wang Y., Daniels J. E., Xiao Y., Ferry M., A high-specific-strength and corrosion-resistant magnesium alloy. Nat. Mater. 14, 1229–1235 (2015).
14
Beaudry B. J., Daane A. H., A study of the scandium-magnesium system from 0 to 60 at.% scandium. J. Less Common Met. 18, 305–308 (1969).
15
Ogawa Y., Ando D., Sutou Y., Koike J., Aging effect of Mg-Sc alloy with α+β two-phase microstructure. J. Jpn. Inst. Met. Mater. 80, 171–175 (2016).
16
Ando D., Ogawa Y., Suzuki T., Sutou Y., Koike J., Age-hardening effect by phase transformation of high Sc containing Mg alloy. Mater. Lett. 161, 5–8 (2015).
17
G. Lütjering, J. C. Williams, Titanium (Springer, 2003).
18
Duerig T. W., Terlinde G. T., Williams J. C., Phase transformations and tensile properties of Ti-10V-2Fe-3Al. Metall. Trans. A 11, 1987–1998 (1980).
19
Lopes E. S. N., Cremasco A., Afonso C. R. M., Caram R., Effects of double aging heat treatment on the microstructure, Vickers hardness and elastic modulus of Ti–Nb alloys. Mater. Charact. 62, 673–680 (2011).
20
Endoh K., Tahara M., Inamura T., Kim H. Y., Hosoda H., Miyazaki S., The effect of aging temperature on morphology of α phase in Ti-3Mo-6Sn-5Zr shape memory alloy. Mater. Today Proc. 2 (suppl. 3), S817–S820 (2015).
21
Ohyama H., Nakamori H., Ashida Y., Maki T., Effects of cold deformation on the morphology of α precipitates in β titanium alloys. ISIJ Int. 32, 222–231 (1992).
22
Kim H. Y., Hashimoto S., Kim J. I., Hosoda H., Miyazaki S., Mechanical properties and shape memory behavior of Ti-Nb alloys. Mater. Trans. 45, 2443–2448 (2004).
23
Baker C., The shape-memory in a titanium-35 wt.-% niobium alloy. Met. Sci. J. 5, 92–100 (1971).
24
Takahashi E., Sakurai T., Watanabe S., Masahashi N., Hanada S., Effect of heat treatment and Sn content on superelasticity in biocompatible TiNbSn alloys. Mater. Trans. 43, 2978–2983 (2002).
25
Fukui Y., Inamura T., Hosoda H., Wakashima K., Miyazaki S., Mechanical properties of a Ti-Nb-Al shape memory alloy. Mater. Trans. 45, 1077–1082 (2004).
26
Maeshima T., Ushimaru S., Yamauchi K., Nishida M., Effects of Sn content and aging conditions on superelasticity in biomedical Ti-Mo-Sn alloys. Mater. Trans. 47, 513–517 (2006).
27
Tomio Y., Furuhara T., Maki T., Effect of cooling rate on superelasticity and microstructure evolution in Ti-10V-2Fe-3Al and Ti-10V-2Fe-3Al-0.2N alloys. Mater. Trans. 50, 2731–2736 (2009).
28
Sutou Y., Omori T., Kainuma R., Ishida K., Grain size dependence of pseudoelasticity in polycrystalline Cu-Al-Mn-based shape memory sheets. Acta Mater. 61, 3842–3850 (2013).
29
Miyazaki S., Otsuka K., Development of shape memory alloys. ISIJ Int. 29, 353–377 (1989).
30
Wang Y., Ren X., Otsuka K., Shape memory effect and superelasticity in a strain glass alloy. Phys. Rev. Lett. 97, 225703 (2006).
31
Materials and methods and supplementary text are available as supplementary materials on Science Online.
32
Gharghouri M. A., Weatherly G. C., Embury J. D., Root J., Study of the mechanical properties of Mg-7.7 at.% Al by in-situ neutron diffraction. Philos. Mag. 79, 1671–1695 (1999).
33
Cáceres C. H., Sumitomo T., Veidt M., Pseudoelastic behavior of cast magnesium AZ91 alloy under cyclic loading-unloading. Acta Mater. 51, 6211–6218 (2003).
34
Thompson W., Calculation of true volume grain diameter. Metallography 5, 366–369 (1972).
35
Inamura T., Kim J. I., Kim H. Y., Hosoda H., Wakashima K., Miyazaki S., Composition dependent crystallography of α′′-martensite in Ti-Nb-based β-titanium alloy. Philos. Mag. 87, 3325–3350 (2007).

(0)eLetters

eLetters is a forum for ongoing peer review. eLetters are not edited, proofread, or indexed, but they are screened. eLetters should provide substantive and scholarly commentary on the article. Embedded figures cannot be submitted, and we discourage the use of figures within eLetters in general. If a figure is essential, please include a link to the figure within the text of the eLetter. Please read our Terms of Service before submitting an eLetter.

Log In to Submit a Response

No eLetters have been published for this article yet.

Information & Authors

Information

Published In

Science
Volume 353 | Issue 6297
22 July 2016

Submission history

Received: 9 March 2016
Accepted: 28 June 2016
Published in print: 22 July 2016

Permissions

Request permissions for this article.

Acknowledgments

We thank N. Ueshima and K. Oikawa (Tohoku University, Japan) for help with the tensile testing experiment; X. Xu, T. Omori, and R. Kainuma (Tohoku University, Japan) for help with the XRD and Physical Property Measurement System experiments; K. Kobayashi and T. Miyazaki (Tohoku University, Japan) for help with TEM measurements; and K. Yoshimi and K. Ishida (Tohoku University, Japan) for fruitful discussions. This work was supported by the Japan Society for the Promotion of Science KAKENHI, Grant-in-Aid for Young Scientists (A), grant no. 15H05549, and Tohoku University Division for International Advanced Research and Education. The present authors are inventors on Japanese patent application no. 2015-201830, applied for by Tohoku University. The data are available from the corresponding authors upon request.

Authors

Affiliations

Yukiko Ogawa
Department of Materials Science, Graduate School of Engineering, Tohoku University, 6-6-11, Aoba-yama, Aoba-ku, Sendai 980-8579, Japan.
Daisuke Ando* [email protected]
Department of Materials Science, Graduate School of Engineering, Tohoku University, 6-6-11, Aoba-yama, Aoba-ku, Sendai 980-8579, Japan.
Department of Materials Science, Graduate School of Engineering, Tohoku University, 6-6-11, Aoba-yama, Aoba-ku, Sendai 980-8579, Japan.
Junichi Koike
Department of Materials Science, Graduate School of Engineering, Tohoku University, 6-6-11, Aoba-yama, Aoba-ku, Sendai 980-8579, Japan.

Notes

*
Corresponding author. Email: [email protected] (D.A.); [email protected] (Y.S.)

Metrics & Citations

Metrics

Article Usage

Altmetrics

Citations

Cite as

Export citation

Select the format you want to export the citation of this publication.

View Options

Check Access

Log in to view the full text

AAAS ID LOGIN

AAAS login provides access to Science for AAAS Members, and access to other journals in the Science family to users who have purchased individual subscriptions.

Log in via OpenAthens.
Log in via Shibboleth.

More options

Register for free to read this article

As a service to the community, this article is available for free. Login or register for free to read this article.

Purchase this issue in print

Buy a single issue of Science for just $15 USD.

View options

PDF format

Download this article as a PDF file

Download PDF

Full Text

FULL TEXT

Media

Figures

Multimedia

Tables

Share

Share

Share article link

Share on social media

Morty Proxy This is a proxified and sanitized view of the page, visit original site.