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Title:
The crystal structure of α-fluorine
Authors:
Pauling, Linus; Keaveny, Ian; Robinson, Arthur B.
Affiliation:
AA(Department of Chemistry, Stanford University, Stanford, California 94305 USA), AB(Department of Chemistry, Stanford University, Stanford, California 94305 USA), AC(Department of Chemistry, Stanford University, Stanford, California 94305 USA)
Publication:
Journal of Solid State Chemistry, Volume 2, Issue 2, p. 225-227.
Publication Date:
08/1970
Origin:
ELSEVIER
Abstract Copyright:
(c) 1970 Elsevier Science B.V. All rights reserved.
DOI:
10.1016/0022-4596(70)90074-5
Bibliographic Code:
1970JSSCh...2..225P

Abstract

The crystal structure of α-fluorine, stable below 45.6°K, has been studied by the theoretical analysis of the crystal energy and by the reinterpretation of the X-ray powder pattern reported by Meyer, Barrett, and Greer. It is concluded that the space group is {C2}/{c}, with eight F in the unit cell, cell dimensions a = 5.50Å, b = 3.28Å, c = 7.28Å, β = 102.17°, in the general positions 8(f), with x = 0.285, y = 0.317, z = 0.0997.
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