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Title:
Investigations of NanoBud formation
Authors:
Nasibulin, Albert G.; Anisimov, Anton S.; Pikhitsa, Peter V.; Jiang, Hua; Brown, David P.; Choi, Mansoo; Kauppinen, Esko I.
Affiliation:
AA(NanoMaterials Group, Laboratory of Physics and Center for New Materials, Helsinki University of Technology, P.O. Box 1000, 02044 Espoo, Finland), AB(NanoMaterials Group, Laboratory of Physics and Center for New Materials, Helsinki University of Technology, P.O. Box 1000, 02044 Espoo, Finland), AC(National CRI Center for Nano Particle Control, Institute of Advanced Machinery and Design, School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-742, Republic of Korea), AD(VTT Biotechnology, P.O. Box 1000, 02044 VTT Espoo, Finland), AE(NanoMaterials Group, Laboratory of Physics and Center for New Materials, Helsinki University of Technology, P.O. Box 1000, 02044 Espoo, Finland), AF(National CRI Center for Nano Particle Control, Institute of Advanced Machinery and Design, School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-742, Republic of Korea), AG(NanoMaterials Group, Laboratory of Physics and Center for New Materials, Helsinki University of Technology, P.O. Box 1000, 02044 Espoo, Finland)
Publication:
Chemical Physics Letters, Volume 446, Issue 1, p. 109-114.
Publication Date:
09/2007
Origin:
ELSEVIER
Abstract Copyright:
(c) 2007 Elsevier B.V.
DOI:
10.1016/j.cplett.2007.08.050
Bibliographic Code:
2007CPL...446..109N

Abstract

The formation of a novel hybrid material, NanoBuds, single-walled carbon nanotubes (CNTs) with covalently attached fullerenes was investigated in a ferrocene-carbon monoxide system. Fullerenes and CNTs were simultaneously formed by carbon monoxide disproportionation on the surface of iron particles in the presence of etching agents such as H 2O and CO 2. On the basis of parametric investigations and in situ sampling of the product from different locations in the reactor the mechanisms for NanoBud formation are discussed.
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