Over 70 years of chemical investigations have shown that plutonium exhibits some of the most complicated chemistry in the periodic table. Six Pu oxidation states have been unambiguously confirmed (0 and +3 to +7), and four different oxidation states can exist simultaneously in solution. We report a new formal oxidation state for plutonium, namely Pu²⁺ in [K(2.2.2-cryptand)][Pu^IICp″₃], Cp″ = C₅H₃(SiMe₃)₂. The synthetic precursor Pu^IIICp″₃ is also reported, comprising the first structural characterization of a Pu-C bond. Absorption spectroscopy and DFT calculations indicate that the Pu²⁺ ion has predominantly a 5f⁶ electron configuration with some 6d mixing.